There are a bunch of Chaos-worshipping xenos in the Gaunt's Ghosts novel Traitor General . I think it's weird that Games Workshop has never developed 'Chaos Xenos' as a troop type in the tabletop gameā¦
If anything, they'd be Chaos Cultists as per Codex: Chaos Space Marines. Though it does strike me as odd how humanity is the only prominent Chaos worshipping race in the setting. Every other race seems to have a resistance/immunity to it.
Kroot sound like they'd make great Khorne cultists, though, and there are Chaos Orks, mostly in the form of Khornate Stormboyz, though this is considered un-Orky by most Orks. It's usually viewed with a mixture of disappointment and exasperation, akin to a teenage 'Wiccan' phase in rebellion against their religious parents. Those that don't grow out of it get krumped.