The best thing is, that even if the subject succeeds on his -20 Psyniscience test, the Psyker can just use Deceive/Influence to say "I haven't used any psychic powers." and problem solved . It is not like neon signs suddenly pop up behind the psyker just because his victim succeeded on an (untrained) Psyniscience skill test.
Also ,as a side note, if the people of the Warhammer 40k universe shouted "Witchcraft!" for every weird and completely-out-of-ordinary thing they encounter then they would never fall silent. That's why they say ignorance is a bliss one should treasure.