The book gives a few examples on which sort of Chaos Space Marines that can make up a given character and specifically mentions recently fallen loyalists and Storm Wardens (the "in-house" Space Marine chapter in Death Watch, p.50).
Now, I imagine playing one of these recently fallen Space Marines will precent a number of unique challenges and obstacles that a veteran Chaos Space Marine would not have to worry about.
Specifically I imagine that it would have to be one tough Space Marine to not end up as the plaything of a more "real" Chaos Space Marine. Skirmishes and out-right war between Space Marines is certainly nothing new in the Vortex but I still cannot shake the feeling that a previously loyal Space Marine that recently fell to chaos and made his way to the Vortex would be seen with very lustfilled/hatefilled eyes by a great many other Chaos Space Marines. Sort of like the new, young and fresh kid that ends up among the hardened criminals in an american jail (if I got my prejudice right).
How likely is he to survive the first few minutes in the Vortex?
How much more bad ass than the Chaos Marines does he have to become in order to stay alive?
Does it even make sense for him to make his way to the Vortex? And if not the Vortex, where would he likely escape the wrath of the Imperium (and his Chapter)?