I've been kicking around an idea where the Kill-team gets caught in the crossfire between two chaos legions over a deamonic artifact, something like a dry, withered heart that contains the spirit of a vanquished bloodthirster. One side wants to chuck it into the sun, thereby releasing the deamon, and the other side wanting to devour it for it's power. Either way, when the brothers get their hands on it they discover that it has a corrupting influence, presenting them with a challenge on how to dispose of it.
Also I've discovered that Thousand Son's disguised as inquisitorial muck-a-mucks are really, really good at stealing freshly liberated xenos/chaos tech from battle brothers right after a mission.