The Grey Knights are bar the Custodes the greatest warriors the imperium has. Each one is utterly fearless, dedicated and trained to fight and stand against the greatest enemy Humanity/Reality has. There is no such thing as a lowly newbie Grey Knight.
The fact that not all of them manifest psy power is not because they have none it’s a matter of safety and training. They channel their psychic might though items such as weapons or as a unit, to protect against corruption, possession, ironically much like the Elder do.
Only the most experienced Grey Knights are deemed pure and strong willed enough to directly project psychic power, you must remember the enemy they fight.
They are Humanities ultimate champions.
Sadly Grey Knights would not fit in a Dark Heresy game as a playable character maybe a Deathwatch game with it missions and objective's providing a focus for these dedicated champions of Humanity, but unless the entire party were Grey Knights a Grey Knight would overwhelm even ascended characters to say nothing of the moral compromises that Acolytes must make. A Soroitas is a hard core Zealot but that’s based on faith. A Gray Knight's Zeal is based on knowledge of the truth concerning their enemy.
Purity is life or death to them literally.