My wife plays a Hired Gun Merc Soldier, Demolitionist based off the character Fiona in Burn Notice. Is there anyone out there that could Photoshop an image to make her look "Star Warsy"? She would really appreciate it.

If possible, her main gun is the Heavy Blaster Rifle the Sandtrooper Commander in Mos Eisley uses in Docking Bay 94...

I'm afraid I can't help you in the photo-manipulation area. Have you looked through the "NPCs...PCs...Monsters...n stuff...art" thread? There's more than 260+ pages. You're bound to find something you like. Barring that, if you can find a piece that you really like, it might be easier to put your desired face on that as opposed to modifying a screen cap to fit another genre.

Good luck!