Better to resist possession, not necessarily stronger. Being good at shooting things doesn't make you a sniper, you should be patient enough to wait for hours before shooting and don't loose your accuracy during this time. In fact, it come way before being good at shooting in the sniper training. Psyker primaris should be able to withstand the stress of a battle and still use their psychic power, it is more important than their raw capacity. Imperial commanders don't need powerful psykers that explode as soon as there are laser beams in the air, they need psykers with enough composure to keep supporting the troops during a fight. There are probably psyker primaris stronger than astropaths, but weaker to.
Being fit to the role doesn't mean being the best in one of its aspects.