If you get an airbrush, grab some plastic armymen and practice on them.
Best primers?
Another plug for an airbrush and vallejo surface primer.
Rattlecans are the worst.
I love Army Painter primers but I also live in the desert. If your climate is dry they work great. If you live somewhere humid they tend to come out a little "textured" when sprayed.
Dupli-color sandable auto primer!
Its the flipping best and comes in a range of colors for only 5 bucks a can.