Just wanted to check something before I flew it. Double Edge with TLT, and Unguided Rockets. If I fire the TLT and the first volley misses, can I fire unguided rockets or primary weapon then fire again for TLT second volley? Then if the second missed can I fire the unguided rockets a second time that round?

No. Follow the timing chart in the FAQ.

For TLT to "miss" now it needs to completely miss meaning neither attack can have uncancelled boom/kabooms after Defense.

Cool, thank you for the clarification