It's part of Legends now, but in the novel Shadows of the Empire, where Luke, Leia, and Vader are all on Coruscant (though not all in the same location), there's a point where Luke reaches out to Leia with the Force, and she responds. Vader picks up on this, is roughly able to determine that it's Luke he's sensing... but there's also a weird sort of "echo" effect as though there were two Force users instead of just the one, since he had no idea who Luke was reaching out to. Vader ultimately writes it off as he was far more focused on "dealing" with the story's main villain Xizor (who'd been a pain in Vader's armor-plated hindquarters throughout the story).
Something similar could have happened at Bespin, where Vader was so focused on just Luke that he ignored anything Leia might have been doing as an untrained Force-sensitive as what amounts to background noise.