I can't be assed to check if anyone has answered this already, but by the core book, getting the same talent twice in the origin path grants you the Talented (Any skill) talent, which is quite handy to have for Dodge and such.
As for being detected as a psyker, any other psyker with the Divination discipline can tell you're a psyker with a simple psyniscience check, using the Aura Reading technique. You're boned.
Regarding Talents:
The Into The Storm supplement provides an alternate rule where you may choose to get 50xp back if a skill / talent is duplicated (As the origin paths in that book cost XP you are effectively getting a discount.)
Regarding Psykers:
Yeah that was one of the powers I asked about in the previous page along with the Navigator's "Gaze into the Abyss" power? "Gaze into the Abyss" is an opposed roll at least but the Aura reading is not even that and I am assuming there are other techniques similar to these two that I don't know about.
Is there any technique by which one may hide their psyker ability? and/or force an opposed roll on things like aura reading?